Chapter 1 Introduction
1.1 The Scope of Chemical Engineering Thermodynamics
1.2 System and Surroundings
1.3 The Chemical State and Fluid Properties
1.4 The First Law of Thermodynamics
1.4.1 The first law of thermodynamics for controlled mass system
1.4.2 The first law of thermodynamics for controlled volume system
1.5 The Second Law of Thermodynamics
1.5.1 The upper limit for the conversion of heat into work
1.5.2 Entropy
1.5.3 Mathematical statement of the second law
Problems
Chapter 2 Volumetric Properties of Fluids
2.1 p-V-T Behavior of Pure Substances
2.2 The Equations of State(EOS)of Fluid
2.2.1 The EOS of ideal gas
2.2.2 Virial equations of state
2.3 Cubic Equations of State
2.3.1 The van der Waals equation of state
2.3.2 The Redlich-Kwong(R-K)equation of state
2.3.3 The Soave-Redlich-Kwong(SRK)equation of state
2.3.4 The Peng-Robinson(P-R)equation of state
2.3.5 A generic cubic equation of state
2.4 Generalized Correlations of Gases
2.4.1 Theorem of corresponding states
2.4.2 Generalized cubic EOS
2.4.3 Two-parameter theorem of corresponding states
2.4.4 Three-parameter theorem of corresponding states
2.4.5 Generalized correlations of the second virial coefficient
2.5 Liquid & Liquid-like Roots of the Generic Cubic EOS
2.6 Generalized Correlations for Liquids
Problems
Chapter 3 Thermodynamic Properties of Fluids
3.1 Property Relations for Homogenous Phases
3.2 Calculations of Enthalpy and Entropy
3.3 Residual Properties
3.4 Residual Properties by EOS
3.5 Calculations of Liquid Enthalpy and Entropy
3.6 Generalized Property Correlations for Gases
3.6.1 Generalized compressibility factor Z for residual enthalpy and residual entropy
3.6.2 Generalized second virial coefficient for residual enthalpy and residual entropy
3.7 Thermodynamic Diagrams
3.8 Tables of Thermodynamic Properties
3.9 T-S Diagrams
3.9.1 Heating and cooling processes at isopiestic pressure
3.9.2 Throttling expansion processes
3.9.3 Isentropic expansion or compression processes
3.10 p-H Diagrams
3.11 H-S Diagrams
Problems
Chapter 4Thermodynamic Properties of Mixtures
4.1 The Mixing Rules
4.2 The Calculations of Vm,mix and Zmix
4.2.1 Amagat’s law(part volume law)combined with Z graphs
4.2.2 EOS for a mixture of real gases
4.3 The Calculations of HR and SR
4.3.1 The calculations of HR and SR by EOS
4.3.2 The calculations of HR and SR by generalized correlation graphs
Problems
Chapter 5 Solution Thermodynamics
5.1 Property Relations for Open Systems and Chemical Potential
5.2 Partial Properties
5.3 Fugacity and Fugacity Coefficient
5.3.1 Fugacity calculations for pure gases
5.3.2 Fugacity calculations for pure liquids
5.3.3 Fugacity calculations for species in solution
5.3.4 Application of Microsoft Excel in the thermodynamic property calculations
5.4 The Ideal Solution and Standard State
5.5 Excess Properties and Property Change in Mixing
5.5.1 Excess properties
5.5.2 Property change in mixing
5.5.3 H-x graph
5.6 Activity and Activity Coefficient
5.6.1 The Wohl type equations
5.6.2 The gamma equation based on local composition
5.6.3 The UNIQUAC and UNIFAC model
Problems
Chapter 6 Phase Equilibrium
6.1 The Criterion of Phases Equilibrium
6.2 Vapor-Liquid Equilibrium
6.2.1 VLE under low pressures
6.2.2 VLE under moderate pressures
6.2.3 VLE under high pressures
6.3 Gas-Liquid Equilibrium
6.4 Liquid-Liquid Equilibrium
6.4.1 LLE phase diagrams
6.4.2 The stability of liquid solution
6.4.3 LLE calculations
6.5 Vapor-Liquid-Liquid Equilibrium (VLLE)
Problems
Chapter 7 Thermodynamics of Flow Process
7.1 Conservation of Mass
7.2 Conservation of Energy
7.3 Entropy Balance
7.3.1 Concept of entropy
7.3.2 Entropy balance
7.4 Processes Analyzed by Thermodynamics Methods
7.4.1 Fluid flowing
7.4.2 Compression process
7.4.3 Expansion process
7.4.4 Throttling process
Problems
Chapter 8Thermodynamics Cycle
8.1 Carnot-Cycle and Its Anticlockwise Cycle
8.2 Rankine-Cycle & Steam Power Plant
8.2.1 Improving of the Carnot engine
8.2.2 Improving of the Rankine engine
8.3 Vapor Compression Refrigeration Cycle
8.4 Absorption Refrigeration
8.5 Heat Pump
8.5.1 A brief historical development of heat pumps
8.5.2 Vapor compression HP
8.5.3 Absorption heat pump
Problems
Chapter 9 Thermodynamic Analysis of Processes
9.1 Ideal Work
9.1.1 Non-flowing process
9.1.2 Steady-state flow process
9.2 Lost Work
9.3 Typical Problems
9.3.1 Tube flow
9.3.2 Heat transfer
9.4 Energy Optimization
Problems
Appendix
Appendix A Conversion Factors and Values of the Gas Constant
Appendix B Properties of Pure Species
Appendix C Heat Capacities and Property Changes of Formation
Appendix D The Lee/Kesler Generalized Correlation Tables
Appendix E Steam Tables
List of Symbols
Selected Glossary in Chemical Engineering Thermodynamics with Chinese Translation
References